Molecularity of a Reaction

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Molecularity of a Reaction: Overview

In this topic, we will learn how to define and calculate the molecularity of a reaction with the help of examples.

Important Questions on Molecularity of a Reaction

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Which statement about molecularity of reaction is not correct?

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For a unimolecular reaction:

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Which reaction called Trimolecular reaction?

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Write a very short note on bimolecular reaction.

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2 HI H2+I2 

The above reaction is an example of 

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2 HI H2+I2 

What is the molecularity of the above reaction?

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Trimolecular reactions are uncommon because:

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If two reactants take part in a reaction, then:

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Give an example for trimolecular reaction ?

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Define trimolecular or termolecular reaction.

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Termolecular reactions involve simultaneous collision between _____ reacting species.(three/ four)

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Which of the reactions shows this kind of example ?

2NO + O2  2NO2

 

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Define unimolecuar reaction ?

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Give an example for an unimolecular reaction.

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If in a unimolecular reaction, AgProducts takes place according to the mechanism

I. A + A k - 1 k 1 A * + A

II. A * k 2 P

where k 1 k - 1   k 2  are the rate constants and P, A and A *  stand for product molecule, normal molecules of reactants and activated molecules of reactants respectively.

Which of the following statements are correct?

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For next two question please follow the same

 If in a unimolecular reaction, Ag products takes place according to the mechanism

I. A + A k - 1 k 1 A * + A

II. A*k2P

where k 1 k - 1   k 2  are the rate constants and P, A and A *  stand for product molecule, normal molecules of reactants and activated molecules of reactants respectively.

Which of the following expressions are correct?

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Order is applicable to elementary as well as complex reactions whereas _____ is applicable only for elementary reactions.

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Consider the reaction Tl+(aq)+2Ce4++(aq)Tl3++(aq)+2Ce3+(aq) 

The rate law for the reaction is rate = k [Ce4+] [Mn2+].

In the presence of Mn2+ the reaction occurs in the following elementary steps:

Ce4+ (aq)+Mn2+(aq)  Ce3+(aq)+Mn3+ (aq)

Ce4+(aq)+Mn3+(aq)Ce3+(aq)+Mn4+(aq)

Tl+(aq)+Mn4+(aq)Tl3+(aq)+Mn2+(aq)

Identify rate determining step.

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The reaction between H2 (g) and ICl (g)occurs in the following steps:
 (i) H2+IClHI+HCl

 (ii) HI+IClI2+HCl

The reaction intermediate in the reaction is

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The rate law for the reaction 2 H2 (g) + 2NO (g)  N2 (g) + 2H2O (g) is given by rate =K [H2] [NO]2. The reaction occurs in the following steps:

H2 + 2NO  N2O + H2ON2O + H2  N2 + H2O
Identify the slow step.